Hapke M. Metallocenes in Regio- and Stereoselective Synthesis 2024 torrent

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This book presents the latest synthetic protocols for the assembly of functionalized Cp ligands and their transition metal complexes. Cyclopentadienyl (Cp) complexes of transition metals belong to the most important classes of transition metal complexes with tightly bound ligands in the coordination sphere since their discovery in the middle of the last century. Even though they have been known for a long time, this field constantly evolves to deliver novel modified Cp ligands and complexes and to blossom into new fields of application. Beside the synthesis of ligands and metal complexes this book concentrates on novel and prospering fields of their application in organic synthesis. In this respect the Cp complexes have been applied to induce and catalyze various significant chemical transformations such as new C-C bond formation involving unsaturated substrates (e.g. cyclotrimerizations, cycloadditions, carbometallations, etc.), C-H bond and C-C bond activations followed by subsequent reactions (e.g. arylation, alkenylations, annulations, etc.), as well as many other processes. This volume also covers the recent development and application of chiral Cp complexes in enantioselective synthesis.
Synthesis and Application of Highly Substituted Cyclopentadienes
Synthesis of 1,2-Disubstituted Cyclopentadienes and Their Application
Synthesis and Application of Novel Chiral Cp Ligands in Transition Metal Catalysis
Planar Chiral Ferrocenes: A Concise Introduction
Knölker-Type Catalysts for (Asymmetric) Hydrogenation Reactions
Selective Transformations Mediated by Group 4 Metal Cyclopentadienyl Complexes
Naturally Occurring Cyclopentadienes and Cyclopentadienyl Anions
Naturally Occurring Diazofluorenes